Hardwood will sag the least. Hardwood plywood like Baltic Birch, then lesser sheet goods, then plastic no matter how well it looks engineered. In other words, plastic makes horrible shelves.
Different hard woods have different degrees of flex under the same load. A good reference: http://workshopcompanion.com/KnowHow/Wood/Hardwoods_&_Softwoods/1_Wood_Botany/1_Wood_Botany.htm
More specific table: http://workshopcompanion.com/KnowHo..._Properties/Mechanical_Properties_Table_1.htm
Different hard woods have different degrees of flex under the same load. A good reference: http://workshopcompanion.com/KnowHow/Wood/Hardwoods_&_Softwoods/1_Wood_Botany/1_Wood_Botany.htm
More specific table: http://workshopcompanion.com/KnowHo..._Properties/Mechanical_Properties_Table_1.htm