If you can hand pick your ply, standard luan will work for the boat, especially if you're glassing it afterward. It won't be as nice or as long-lasting (without maintenance finishes every couple of years) as a marine-grade ply boat but it will work just fine. I haven't found marine grade ply to be particularly expensive compared to pressure treated stuff, though. I guess it's all relative.
More importantly, for a boat, I wouldn't want to use pressure treated anything because it's pretty toxic stuff and doesn't look as nice either.
EDIT: I agree, brass screws won't be your best option for hardware. Check out some of the boat building forums, like kayakbuildersforum, or chesapeake light craft (clc.com) forums for some great advice.