Several questions and comments...
Assume you are going to paint this?
If yes then filler is your friend even if you do get a good joint.
From a clamping perspective when I put my 14' bench top together I screwed blocks on about 3-4" from the joint and used them to clamp the 2 pieces together, this method requires clamps less than a foot long. In my case I was using 2 sheets(double thickness) with an offset joint so I let the bottom piece provide the alignment. In your case you would need your support pieces to keep the surfaces flat to each other. You will have screw holes to fill...
When screwing into many hard surfaces the screw starting tends to lift your piece off of the surface, and it wont draw tight. I either back the screw out after the first tightening and do it again to cinch it tight, or I pre-drill the holes. I'm typically in a hurry so I used the first method most often.