Is the den going to be exposed to the weather? If not as wide as the bent board is you need use bendable plywood. The stuff bends like rubber. It doesn't have an attractive veneer for the finish layer like most plywood. It would be necessary to veneer over the den after it is assembled.
An alternative would be to make narrow strips of solid wood like slats and bend around a form. You would have to make a steam chamber to steam the wood to soften it to allow it to bend. This could be as simple as a pvc pipe rigged to vent steam through.
An alternative would be to make narrow strips of solid wood like slats and bend around a form. You would have to make a steam chamber to steam the wood to soften it to allow it to bend. This could be as simple as a pvc pipe rigged to vent steam through.